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Peracetic acid and other sanitisers

What sanitiser should be used on cider equipment?

In short

Peracetic acid is supplied as an equilibrium mixture of peracetic acid, hydrogen peroxide, acetic acid and water. It kills by oxidation, works quickly and works in cold water, and its breakdown products are things cider already contains.

It is used at a very high dilution from a concentrate, and at that use dilution many formulations are approved as no-rinse. The concentrate is corrosive and its vapour is an irritant.

No sanitiser is a substitute for cleaning. All of them are degraded by organic soil, and all of them assume a clean surface underneath.

Why peracetic acid is the industry default

It is fast, effective against yeasts, moulds and bacteria including the lactic and acetic organisms that matter in cider, and it works at ambient temperature, which saves the energy that a hot sanitisation would need. It is effective across a wide pH range and it does not leave a film.

Its breakdown products are the second reason. Peracetic acid decomposes to acetic acid, water and oxygen, so the residue at a use dilution is a trace of vinegar in a drink that already contains some. That is why it is accepted as a no-rinse sanitiser where the formulation and the jurisdiction allow it, and it removes the rinse step that would otherwise reintroduce whatever the water supply carries.

It is also unstable, which is a practical constraint rather than a defect. A made-up solution loses strength over hours to days depending on temperature, water quality and what it has been used on, so solutions are made fresh and their strength is checked with test strips or a titration rather than assumed from the dilution.

The alternatives

The chlorine row deserves emphasis in a cider context. Hypochlorite is cheap, familiar and widely used in domestic cleaning, and it is a poor choice in a cider house: it pits stainless steel, and chlorine reacting with phenolic material forms chlorophenols which micro-organisms convert to haloanisoles, the compounds behind musty taint. A cellar with a chlorine habit can develop a taint problem that survives long after the practice stops.

Sanitisers used on cider equipment
SanitiserHow it worksStrengthsLimitations
Peracetic acidOxidationFast, cold-water, no-rinse at use dilution, benign breakdown productsCorrosive concentrate; unstable in solution; irritant vapour
Acid-anionic (phosphoric acid with a surfactant)Low pH plus surfactant disruption of cell membranesStable, leaves an acidic surface, also removes light scaleFoams, which is a problem in a circulating system; needs contact time
IodophorIodine released from a carrierEffective, low use concentrationStains plastic; can taint at higher concentrations; sensitive to temperature
Chlorine-based (hypochlorite, chlorine dioxide)OxidationCheap and effectiveCorrodes stainless; a documented route to chlorophenol and haloanisole taint; must never contact acid
Hot water and steamThermal destructionNo chemical residue at allEnergy-hungry; needs a defined temperature held for a defined time to mean anything; thermal stress on vessels
OzoneOxidation by dissolved ozone gasLeaves nothing but oxygen; effective coldGenerator required; ozone gas is toxic to breathe; corrodes some materials

Handling peracetic acid

The concentrate is dangerousPeracetic acid concentrate is corrosive to skin, eyes and the respiratory tract, and its vapour is a strong irritant even at low concentrations. It reacts vigorously with alkalis and with reducing agents and must never be mixed with any other cleaning chemical. It is decanted and diluted in a ventilated place, with the eye and skin protection the safety data sheet specifies, and it is stored in its original vented container away from heat and away from anything it might react with. The dilution, contact time and whether a rinse is required are properties of the specific product and are given on its label; those instructions govern, and no figure recalled from elsewhere should be substituted for them.

Getting a sanitiser to work

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