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Cider science

Reading a juice analysis

What do the numbers on a juice analysis actually tell me?

In short

A full juice analysis answers three different questions, and the figures that answer each one are not the ones a beginner expects. Gravity answers how strong the cider will be. pH and nitrogen answer whether the ferment will go cleanly. Acid and tannin answer what it will taste like.

The most useful readings are pairs. Gravity alone is potential alcohol; gravity with acid is whether that alcohol will taste of anything. pH alone is a number; pH with titratable acidity tells you how well buffered the juice is. Nitrogen alone is a concentration; nitrogen against the gravity tells you whether there is enough of it for the amount of sugar the yeast has to get through.

Nothing on an analysis predicts a finished cider. What it does is tell a maker which decisions are still open and which have already been taken by the fruit.

Same pH, twice the acidTwo juices reading pH 3.6 on the same meter, one carrying twice the titratable acidity of the other. Buffering is the reason, and it is why a cider maker measures both.Juice A4 of 8 acid units4.0 g/LJuice B8 of 8 acid units8.0 g/LBoth read pH 3.6 on the meterBuffering is whyMalic acid is weak, so most of it sitsundissociated; its potassium salts absorbadded hydrogen ions. The titration findsevery acid group. The meter finds only free ones.
Two juices reading pH 3.6 on the same meter, one carrying twice the titratable acidity of the other. Buffering is the reason, and it is why a cider maker measures both.
Described in full
Shape
Two panels side by side, each representing a juice. Each panel contains eight small squares in two rows, standing for units of acid: the left panel has four filled and four drawn in dashed outline, the right has all eight filled. Beneath each is its titratable acidity — 4.0 and 8.0 grams per litre. A single wide band below both, with arrows leading into it from each panel, states that both read pH 3.6.
What the squares count
Acid groups available to a titration. The titration finds every one of them, dissociated or not, because the alkali drives the equilibrium until all of them have reacted. That is what titratable acidity measures: how much acid is present.
What the meter finds
Only the hydrogen ions actually free in solution at that moment. Malic acid is a weak acid, so most of it sits undissociated at cider pH, and the free fraction is a small part of the total.
Buffering
The juice also contains the potassium salts of its own acids, and those salts absorb added hydrogen ions. A juice rich in potassium therefore holds a higher pH than its acid content alone would predict, which is how two juices with very different acid loads arrive at the same meter reading.
Why it matters
Perceived sourness follows the amount of acid; microbial risk and sulphite effectiveness follow pH. A maker who measures only one of the two is blind to whichever question the other answers, and the two questions have different answers on the same juice.

The figures, and what each one governs

What each juice measurement decides, and when the decision has to be taken.
FigureWhat it governsWhen it matters
Specific gravity or BrixPotential alcohol, and bodyBefore pressing — it is fixed by the fruit and the ripeness
Titratable acidityPerceived sharpness; whether the cider tastes of anythingAt blending, when it can still be corrected
pHSulphite effectiveness, bacterial risk, protein stabilityBefore sulphiting, because the dose depends on it
Assimilable nitrogenWhether the ferment finishes, and whether it makes sulphideBefore pitching — much easier than afterwards
Total phenolics or tanninBitterness, astringency, colour, ageing capacityAt blending
Sorbitol (perry)Sweetness that will survive the fermentRarely measured; usually inferred
PectinWhether the juice will keeve, and whether it will clearBefore deciding on keeving or enzyme

Read gravity and acid together

A gravity of 1.055 means roughly 7 per cent potential alcohol, and that is all it means. Whether the resulting drink is worth making depends on what else is in the juice, and the figure that decides it most often is acid.

The Long Ashton bittersweets illustrate the problem. Dabinett at 0.18 per cent acid and Médaille d’Or at 0.27 will both ferment to a respectable strength and neither, alone, gives a drink with any lift to it. That is why the West Country tradition blends bittersweets with sharps rather than treating a high-gravity bittersweet as a complete cider. The exceptions — the fruit that carries acid and tannin at once — are the small group of vintage cultivars that single-variety cider is made from.

In the other direction, a sharp apple at 1.045 and 0.9 per cent acid gives a low-strength drink that tastes aggressive. Neither figure is a defect; the combination is.

Read pH and acid together

These two are not interchangeable and neither predicts the other, which is the single most consequential misunderstanding on a juice bench. Titratable acidity counts how much acid is present; pH measures how much of it is dissociated. Buffering — chiefly by the potassium salts of malic acid — decouples them, so two juices with the same acid load can sit at noticeably different pH values.

Which one to act on depends on what is being decided. If the question is whether the cider will taste flat, read the acid. If the question is what sulphite dose to use, read the pH: the molecular fraction of sulphur dioxide, which is the part that actually does the work, collapses as pH rises, and a dose calculated without the pH is a guess.

Read nitrogen against gravity, not on its own

The yeast has to convert all the sugar in the juice, and the nitrogen requirement scales with how much sugar that is. A hundred milligrams per litre of assimilable nitrogen is comfortable in a juice at 1.045 and marginal in one at 1.070, because the second juice asks the yeast to do half as much work again on the same ration.

Below roughly 100 milligrams per litre a cider ferment is generally expected to need thinking about, and the published work supports treating that as a prompt rather than as a threshold. The relationship between low nitrogen and hydrogen sulphide is real and it is not deterministic: studies find ferments at low nitrogen that produce little sulphide and ferments at adequate nitrogen that produce some, and the strain of yeast matters as much as the concentration.

In perry the question is sharper, because pear juice runs far lower and because a total amino acid figure flatters it badly. See the perry chemistry page for why.

The nuance CiderHQ keeps insisting on“Low nitrogen causes sulphide” is a tendency with documented exceptions, not a rule. Reported strongly enough, it leads a maker to add nutrient to a ferment that did not need it and to conclude that a sulphurous ferment was starved when the strain, the temperature or the sulphite regime may have done more.

What a single analysis cannot tell you

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