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Fault

Metal haze

A haze or dark cast caused by dissolved iron or copper picked up from equipment, forming insoluble complexes with phosphate or with the cider’s phenolics.

Also called iron casse, copper casse, metal casse.

Severity
Quality — the drink is worse for it
Where it starts
Pressing, Maturation, Stabilisation, Orchard, Harvest, Juice treatment
Can it be fixed?
Yes, if caught in time
When you notice it
Pressing, Maturation, Packaging
Signs
5 recorded

What it is

Metal haze is a clarity fault caused by metal ions in solution rather than by anything biological or from the fruit. Iron picked up from bare steel, from an old press or from unsuitable fittings forms insoluble complexes with phosphate and with phenolic material, giving a bluish-grey or inky cast; copper from brass fittings or from copper treatment can form a reddish-brown haze under reducing conditions. Both are rarer than they once were, because stainless steel and food-grade plastic have replaced the equipment that caused them.

What you notice

Grouped by sense, because that is how the fault presents itself rather than how it works.

To look at

  • A grey, bluish or inky cast rather than a simple cloudiness
  • A brown-red haze appearing in bottle after a period under reducing conditionsThe copper form, and it often appears after some time in a sealed bottle rather than in tank.

How the batch behaves

  • Haze developing after the cider was exposed to air, in the iron case
  • A cider handled through brass taps, an old press or bare steel

On the palate

  • A metallic, inky taste alongside the haze

When it appears. Some time after contact with the metal responsible, which may have been a press, a fitting, a tank or a single unsuitable tap.

What is known about detecting it

The diagnosis is usually made from the equipment rather than from the glass: a haze that appeared after a change of press, fitting or vessel is worth investigating as a metal problem before anything else.

Peter Mitchell / Cider and Perry Academy, Andrew Lea

What it is mistaken for, and how to tell

One observation per rival, chosen because it separates them rather than because it describes either. Several of these are not faults at all — a style feature, a normal outcome, or the fruit behaving as it does.

What is actually happening

The chemistry or microbiology behind it. Understanding the mechanism is what makes the prevention make sense rather than being a list of rules.

Iron in cider is mostly present as ferrous iron. On exposure to oxygen it is oxidised to ferric iron, which is far less soluble and readily forms complexes: with phosphate, giving the classic white-to-grey ferric phosphate casse, and with phenolic compounds, giving the darker, inky ferric-tannate colouration familiar from iron gall ink. The reaction is the same chemistry, in a drink.

Copper behaves in the opposite direction. Under the reducing conditions inside a sealed bottle, cupric copper is reduced to cuprous, which combines with proteins and with sulphur compounds to form a colloid that appears as a reddish-brown haze. This is why copper casse tends to appear after bottling rather than in tank.

Both metals are also powerful catalysts of oxidation, cycling between oxidation states and allowing oxygen to be reduced to hydrogen peroxide. A cider carrying enough iron or copper to haze is a cider that will also oxidise faster than it should, and the metallic taint and the haze usually arrive together.

Citric acid and other chelators bind the metal ions and keep them in solution, which is the basis of the classical remedy. Removal proper requires a treatment that binds and precipitates the metal, and those are regulated and analytically controlled operations rather than home procedures.

How it happens

Causes, with the stage each originates at and how often it is the explanation.
CauseStageHow often
Bare iron or mild steel anywhere in the cider pathOld presses, unpainted frames and rusted fittings are the classic sources.Pressingoccasional
Brass taps and fittings, which release copper and zincMaturationoccasional
Copper treatment for sulphur compounds, leaving residual copperStabilisationrare
Copper-containing orchard sprays carried in on the fruitOrchardrare
Soil and grit on windfall fruit contributing ironHarvestrare
Galvanised or unsuitable containers used for juice or ciderJuice treatmentrare

Can it be put right?

Most cider faults cannot be reversed. Where that is the answer it is given plainly — an honest 'this batch is what it is' is more useful than a procedure that will not work.

Corrective options and how well each actually works.
OptionEffectivenessWhat it involves
Remove the source and prevent recurrenceReliableThe only action that reliably solves the problem, and it applies to next season rather than to this batch.
Fine or filter out the precipitated hazePartialRemoves the visible complex. The dissolved metal remains and can haze again, and continues to catalyse oxidation.
Add citric acid to chelate the metalPartialThe traditional treatment for iron casse, and it does hold the metal in solution. It adds acidity, which may or may not suit the cider, and any addition should be small and trialled on a sample first.
Blend into a larger clean volumePartialLowers the metal concentration below the level at which it hazes, if a suitable batch is available.
Treat with a metal-removing agentUnlikely to workSuch products exist, are regulated, and require an analytical measurement of the metal concentration to be used correctly. Not a home procedure, and CiderHQ publishes no dose.
On dosages

CiderHQ gives no additive dosage figures. An addition is a food-safety decision that depends on legal limits, on the juice in front of you and on what you are protecting against, and the right figure comes from your supplier’s or regulator’s own guidance rather than from a general reference.

Preventing it

More on this

Metal haze is largely a historical fault, and the reason is worth stating: the equipment that caused it has mostly been replaced. A cellar of stainless steel, plastic and wood does not put iron or copper into cider, and a maker who has never used a brass tap will probably never see this.

It survives in two places. The first is old equipment, particularly presses and mills that have been in a barn for decades and have rusted or lost their plating. The second is deliberate copper treatment for sulphur faults, which introduces the metal on purpose and leaves whatever was not consumed.

The haze is not the main problem it announces. Iron and copper are catalysts of oxidation, and their presence at hazing concentrations means the cider is being oxidised faster than it should be. A cider with a metal haze usually also has a metallic taste and a prematurely aged character.

The chemistry has a pleasing historical resonance. Ferric-tannate complexes, which give the inky cast of iron casse, are the same compounds as iron gall ink — the ink of medieval manuscripts. It is the same reaction between iron and plant phenolics, occurring where nobody wanted it.

The compounds involved

Where in the process it arises

Faults it is confused with

These present similarly. What separates them is set out on each page.

Where this comes up in a guide

The link lands on the step where the fault arises rather than at the top of the pathway, because that is where the decision that causes it is taken.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.