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Compound

Glycerol

A syrupy three-carbon alcohol yeast produces as a side reaction of fermentation, which adds weight to a dry cider and is the raw material for one of its more obscure faults.

Also called Glycerine, Propane-1,2,3-triol.

Class
Alcohols
Formula
C3H8O3
How often it matters
Regularly encountered

What it does in cider

How it is perceived

What the compound registers as, and at roughly what concentration. Perception is not a property of the molecule alone: sugar, tannin and carbonation all change where a threshold falls.

On threshold

Detection in a complex drink is poor: glycerol is usually credited with more textural effect than controlled trials support, and in cider it typically sits well below the concentration at which it can be reliably picked out on its own.

Descriptors it is responsible for

Sensory records that name Glycerol as a cause. Each states the perception and the mechanism behind it.

The structure it moves

Structural dimensions this compound contributes to. Direction and amount depend on concentration and on what else is in the drink; the dimensions themselves are set out in full under Sensory.
DimensionWhat it is
BodyHow much weight and viscosity the drink has in the mouth.
SweetnessHow sweet the drink tastes, which is not the same as how much sugar it contains.

Measured figures

Shown as they were measured, with the context each was taken in. They are not averaged: a concentration recorded in one country's fruit in one decade is not a constant.

Glycerol3.6–4.8 g/L

Villaviciosa, Asturias, Spain, 2001–2002 · 4 samples · HPLC · Suárez Valles, Pando Bedriñana, Fernández Tascón, Querol Simón and Rodríguez Madrera, Food Microbiology 24(1):25–31

Cider fermented at cellar temperature, 12–15 °C. The authors note that cold fermentation raises glycerol, so a warm ferment of the same juice would be expected to finish lower; the figure belongs to the temperature as much as to the fruit.

A fermentation by-product that adds weight and a faint sweetness without being a sugar. Measured in grams per litre.

What forms it

Processes that put this compound into the drink, or increase how much of it is there.

Faults it is implicated in

Being implicated is not the same as being a fault. Several of the compounds on this site are ordinary constituents of a sound cider and define a named fault only above a concentration.

Organisms that produce it

Which organism is responsible usually decides whether the compound is a feature or a symptom.

About Glycerol

In the first hours of fermentation, before ethanol production is running freely, yeast has more reducing power than it can use and dumps the excess by making glycerol. The amount produced is therefore set by conditions at the start of the ferment rather than at the end, and it survives fermentation untouched because Saccharomyces has no reason to consume it again. A typical cider carries a few grams per litre — enough to matter alongside a residual sugar of zero, and one of the reasons a well-made dry cider has a rounder texture than the analysis predicts.

Anything that osmotically stresses the yeast pushes production up. Ice cider, where the juice may start at three times ordinary sugar concentration, ends with markedly more glycerol than an ordinary ferment; so does juice from fruit heavily infected with Botrytis cinerea, because the mould itself makes glycerol before the yeast ever arrives. Cool, slow ferments and certain non-Saccharomyces yeasts, Torulaspora delbrueckii among them, also raise it.

Its less welcome career begins in storage. Lactobacillus collinoides can dehydrate glycerol to acrolein, a sharply reactive aldehyde that then combines with procyanidins to give an intense, lingering bitterness quite unlike tannin bitterness. This is the amertume of old French and English cellar literature, and it explains why a cider can be sound at bottling and bitter two years later without any obvious spoilage having occurred.

Related compounds

Compounds it is formed from, converted into, confused with, or routinely met alongside.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.