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Comparison

Volatile acidity vs ethyl acetate

What is the difference between volatile acidity and ethyl acetate in cider?

In short

Volatile acidity in cider is overwhelmingly acetic acid, produced when acetic acid bacteria oxidise ethanol in the presence of oxygen. It presents as a vinegar smell and a sharp sourness on the palate.

Ethyl acetate is the ester formed from acetic acid and ethanol. It smells of solvent, nail varnish and pear drops, and its sensory threshold is much lower than that of acetic acid — so a cider can smell of solvent well before it tastes of vinegar.

They usually appear together, because the same bacterial activity that raises acetic acid provides the substrate for the ester. Small amounts of ethyl acetate arise from ordinary fermentation and are part of normal cider aroma; a rising level alongside vinegar character is a different signal, and it means the cider is still deteriorating.

The two things being compared

Each side described in its own terms first, so the table below has something to hang on.

Where they differ

Dimension by dimension. Where a row needs a qualification, it carries one rather than being simplified until it fits.

Volatile acidity and Ethyl acetate compared. Neither column is the baseline the other is measured against.
DimensionVolatile acidityEthyl acetate
CompoundAcetic acid.Ethyl acetate.
AromaVinegar.Solvent, nail varnish, pear drops.
TasteSharp and sour on the palate.Chiefly an aroma; contributes little sourness.
Sensory thresholdHigher.Much lower, so it is usually detected first.
OriginAcetic acid bacteria with oxygen; also lactic bacteria in some circumstances.Esterification of acetic acid with ethanol, and in small amounts from ordinary yeast metabolism.
Normal at low levelNeither compound is abnormal in itself. Both are faults at concentration and when rising.A small amount is present in every cider.Also present, and part of normal fruit-ester aroma.
What it signalsOxygen exposure and a bacterial population.The same, usually a step further on.
RemedyPrevention — full vessels, hygiene, sulphite. Once high, blending is the only partial option.The same; the ester cannot be removed at scale.

Notes under a dimension name qualify the whole row, not one column.

When Volatile acidity is the relevant one

The circumstances in which this is the thing being described, rather than a reason to prefer it.

When Ethyl acetate is the relevant one

The circumstances in which this is the thing being described, rather than a reason to prefer it.

A misconception worth clearing up

This comparison exists partly because of the claim below, which is repeated often enough that most readers arrive holding it.

Commonly said

Volatile acidity and ethyl acetate are two names for the same fault.

What is actually the case: They are distinct compounds. Volatile acidity is what is measured and reported analytically; ethyl acetate is a separate ester with a far lower threshold, which is why a cider can be flagged as solventy on the nose while its measured volatile acidity is still unremarkable.

Related comparisons

Distinctions that turn on the same thing, or that this one is routinely confused with.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.