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Fault

Ethyl acetate taint

A solvent, nail-varnish or pear-drop aroma from ethyl acetate, the most abundant ester in cider and the one that turns from lift to fault over a narrow range.

Also called solvent character, nail varnish note.

Severity
Quality — the drink is worse for it
Where it starts
Fermentation, Maturation, Juice treatment
Can it be fixed?
Yes, if caught in time
When you notice it
Fermentation, Maturation, Storage
Signs
5 recorded

What it is

Ethyl acetate is the ester of ethanol and acetic acid, and it is present in every cider ever made. At low concentration it reads as fruit and gives a general impression of lift and freshness. Above a fairly narrow band it stops smelling of fruit and starts smelling of solvent — nail varnish remover, model glue, or the sharper end of a pear drop — and it becomes the first thing the nose finds. It is closely tied to volatile acidity but is a distinct perception with its own causes.

What you notice

Grouped by sense, because that is how the fault presents itself rather than how it works.

On the nose

  • A nail-varnish or glue note that hits the top of the nose before any apple does
  • An exaggerated pear-drop or boiled-sweet character in a cider that should not have one
  • A stinging, almost anaesthetic quality at the back of the nose in a strongly affected sample

On the palate

  • A thin, hollow palate underneath an aggressive noseEthyl acetate is far more assertive in aroma than in flavour, so the cider smells stronger than it tastes.

How the batch behaves

  • A cider that smells markedly worse after being left in the glass for a few minutes

The words for it: Nail varnish, Pear drop, Glue, Solvent, Acetone. Each links to what produces it.

When it appears. Can appear early, from apiculate yeasts in the first days of a spontaneous ferment, or slowly during maturation as acetic acid esterifies with ethanol. The early kind often fades; the slow kind does not.

What is known about detecting it

The odour threshold is far below that of acetic acid, which is why a cider can smell strongly of solvent at an analytical volatile acidity that is not itself extreme. This is the main reason the two faults are reported together: the palate does not separate them, and the arithmetic does not predict which will dominate.

Andrew Lea

What it is mistaken for, and how to tell

One observation per rival, chosen because it separates them rather than because it describes either. Several of these are not faults at all — a style feature, a normal outcome, or the fruit behaving as it does.

What is actually happening

The chemistry or microbiology behind it. Understanding the mechanism is what makes the prevention make sense rather than being a list of rules.

Ethyl acetate is formed enzymatically by yeast, through alcohol acetyltransferase acting on acetyl-CoA and ethanol, and chemically over time by slow esterification of acetic acid with ethanol. The enzymatic route dominates during fermentation; the chemical route dominates in a cider that has been sitting with a raised acetic acid content for months.

The organisms matter. Apiculate yeasts — Hanseniaspora valbyensis, Hanseniaspora uvarum and Kloeckera apiculata — are prolific ethyl acetate producers and are exactly the yeasts that dominate the first days of a spontaneous ferment before ethanol accumulates and Saccharomyces cerevisiae takes over. Film-forming yeasts such as Pichia membranifaciens and Candida species produce large amounts of it at the surface of a standing vessel, which is why a film and a solvent nose so often appear together.

The perceptual problem is the ratio of threshold to typical concentration. Ethyl acetate is detectable at concentrations well below those of most other cider esters, so the gap between the amount that contributes fruitiness and the amount that reads unmistakably as solvent is narrow. Once the drink is over that line, no other aroma survives, because the nose fixes on the most volatile and most irritating component present.

It is also why acetified cider smells of pear drops as well as vinegar: the acetic acid produced by the bacteria is slowly converted into the ester that the nose finds far more readily than the acid itself.

How it happens

Causes, with the stage each originates at and how often it is the explanation.
CauseStageHow often
A long, cool, uninoculated start in which apiculate yeasts dominate for days before Saccharomyces takes overFermentationcommon
A surface film of yeast on a standing vesselMaturationcommon
Raised acetic acid slowly esterifying during long storageMaturationcommon
Fermentation at an unusually high temperature, raising overall ester productionFermentationoccasional
Juice standing warm and unprotected between pressing and the start of fermentationJuice treatmentoccasional

Can it be put right?

Most cider faults cannot be reversed. Where that is the answer it is given plainly — an honest 'this batch is what it is' is more useful than a procedure that will not work.

Corrective options and how well each actually works.
OptionEffectivenessWhat it involves
Treat it as an early warning and secure the rest of the cellarReliableA solvent nose usually means air, a film or an acetic population somewhere. Finding and correcting that protects the batches that are still sound.
Blend into a larger volume of clean ciderPartialBecause the fault is perceived against a threshold, dilution can genuinely put it back below the line. Bench trial first.
Let a lightly affected cider rest in a sealed vesselUnlikely to workSome volatile loss occurs slowly during racking and maturation, but it is small and unreliable, and the same period allows more ester to form from any acetic acid present.
Remove ethyl acetate from finished ciderNot possibleNo practical domestic method exists. Do not attempt any heating, stripping or reduction process to drive it off; that is an operation with real burn and fire risk and it will strip everything else worth having.
On dosages

CiderHQ gives no additive dosage figures. An addition is a food-safety decision that depends on legal limits, on the juice in front of you and on what you are protecting against, and the right figure comes from your supplier’s or regulator’s own guidance rather than from a general reference.

Preventing it

More on this

Ethyl acetate is a good example of a compound that is not a fault until it is. Every cider contains it, a fair amount of what people describe as fruitiness in a young cider is partly it, and the same molecule at a higher concentration is what people mean when they say a drink smells of nail varnish.

For anyone fermenting without an added yeast, the practical lever is time rather than technique. The apiculate yeasts that make the most of it are outcompeted once ethanol rises, so a ferment that starts promptly spends a short time in the phase that produces it and a long ferment that struggles to get going spends much longer.

The diagnostic value of the fault is high. Solvent on the nose of a maturing cider is a reliable signal that oxygen is reaching the liquid somewhere, and it is usually worth acting on before the vinegar note that follows becomes obvious.

It should not be confused with the genuine pear-drop character of some perries and of certain cider styles, where isoamyl acetate rather than ethyl acetate is doing the work. The distinction is in the edge: isoamyl acetate reads as banana and boiled sweet, ethyl acetate reads as sharp and chemical, and once noticed the difference is not subtle.

The compounds involved

The organisms involved

Where in the process it arises

Faults it is confused with

These present similarly. What separates them is set out on each page.

Where this comes up in a guide

The link lands on the step where the fault arises rather than at the top of the pathway, because that is where the decision that causes it is taken.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.