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Compound

Isoamyl acetate

The banana and pear-drop ester, made by yeast from isoamyl alcohol, and one of the clearest chemical signatures of a warm fermentation.

Also called 3-methylbutyl acetate, Banana ester.

Class
Esters
Formula
C7H14O2
How often it matters
Regularly encountered

What it does in cider

How it is perceived

What the compound registers as, and at roughly what concentration. Perception is not a property of the molecule alone: sugar, tannin and carbonation all change where a threshold falls.

On threshold

Detected in the region of a few tens of micrograms per litre — low enough that it is present above threshold in most ciders and dominant in warm-fermented ones.

Descriptors it is responsible for

Sensory records that name Isoamyl acetate as a cause. Each states the perception and the mechanism behind it.

The structure it moves

Structural dimensions this compound contributes to. Direction and amount depend on concentration and on what else is in the drink; the dimensions themselves are set out in full under Sensory.
DimensionWhat it is
Fruit characterHow strongly the drink smells of apple or pear, and of fruit generally.
Fermentation characterAromas made by the ferment rather than carried in from the fruit.

What forms it

Processes that put this compound into the drink, or increase how much of it is there.

What removes or limits it

Processes that reduce it, hold it below a threshold, or stop it forming in the first place.

Faults it is implicated in

Being implicated is not the same as being a fault. Several of the compounds on this site are ordinary constituents of a sound cider and define a named fault only above a concentration.

Organisms that produce it

Which organism is responsible usually decides whether the compound is a feature or a symptom.

About Isoamyl acetate

The banana note in a cider is one molecule, and it is not in the fruit. Yeast makes isoamyl acetate by joining isoamyl alcohol to an acetyl group, using an enzyme whose activity is strongly affected by temperature and by the presence of oxygen and unsaturated fatty acids. A ferment run warm, in a juice with little oxygen exposure, makes a lot of it; the same juice fermented cool with the same yeast makes markedly less.

Because the ester is perceptible at roughly a thousandth of the concentration its parent alcohol needs, the practical consequence of moving a fermentation from 12 °C to 20 °C is out of proportion to the chemistry involved. This is the single most reliable lever a cidermaker has over fruit-estery character, and it is available to anyone who can control tank temperature.

It is also transient. Ester formation and ester hydrolysis are the same reaction run in opposite directions, and in a finished cider the equilibrium favours hydrolysis. A cider that smelled emphatically of banana at bottling will not smell of it three years later, and this is a normal part of ageing rather than a failure of the bottle.

Related compounds

Compounds it is formed from, converted into, confused with, or routinely met alongside.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.