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Compound

Pectin

The structural polysaccharide of fruit cell walls, which decides how much juice a press releases, whether a cider ever clears, and whether keeving is possible at all.

Also called Pectic substances, Protopectin.

Class
Polysaccharides
Formula
Not a single molecule — see below
How often it matters
Present in every cider

What it does in cider

How it is perceived

What the compound registers as, and at roughly what concentration. Perception is not a property of the molecule alone: sugar, tannin and carbonation all change where a threshold falls.

On threshold

Not tasted or smelled directly. What a drinker perceives is texture and clarity: the same cider with and without pectinase treatment differs visibly in the glass and slightly in weight on the palate.

Descriptors it is responsible for

Sensory records that name Pectin as a cause. Each states the perception and the mechanism behind it.

The structure it moves

Structural dimensions this compound contributes to. Direction and amount depend on concentration and on what else is in the drink; the dimensions themselves are set out in full under Sensory.
DimensionWhat it is
BodyHow much weight and viscosity the drink has in the mouth.

Measured figures

Shown as they were measured, with the context each was taken in. They are not averaged: a concentration recorded in one country's fruit in one decade is not a constant.

Pectin0.5–2.5 g/L

context not recorded · Andrew Lea

Read this as an order of magnitude, not a specification. Pectin is a family of polymers rather than one compound, reported figures depend entirely on the assay used, and most of the fruit’s pectin never leaves the pomace at all. Maceration time, milling severity and the fruit’s own enzyme activity move the juice figure more than cultivar does.

Structural polysaccharide that holds haze and enables keeving. Measured in grams per litre.

What forms it

Processes that put this compound into the drink, or increase how much of it is there.

What removes or limits it

Processes that reduce it, hold it below a threshold, or stop it forming in the first place.

Faults it is implicated in

Being implicated is not the same as being a fault. Several of the compounds on this site are ordinary constituents of a sound cider and define a named fault only above a concentration.

Organisms that produce it

Which organism is responsible usually decides whether the compound is a feature or a symptom.

About Pectin

Pectin is the mortar of plant tissue: long chains of galacturonic acid, many of them esterified with methyl groups, interrupted by branched regions carrying neutral sugar side chains. In an unripe apple it is present as insoluble protopectin, locked into the cell wall and holding the fruit hard. Ripening solubilises it, which is why fruit softens, and milling and pressing release a portion of the soluble fraction into the juice. How much gets there depends on how hard the fruit was milled, how long the pomace sat before pressing, and how far the fruit’s own enzymes had already gone.

In the juice, pectin causes two distinct problems that are often confused. The first is mechanical: pectin makes juice viscous and holds water in the pomace, so a pectin-rich mill flows slowly through a press and gives up less juice. The second is colloidal: the dissolved polymer is charged and heavily hydrated, and it keeps fine solids in suspension indefinitely. A pectin haze does not settle, does not respond to fining and blinds a filter, and it is diagnosed not by looking at it but by mixing a sample of the cider with an equal volume of alcohol, which precipitates pectin as visible gelatinous clots. The answer, where clarity is wanted, is a pectinase preparation applied to the juice or to the pomace, which cuts the chains and dismantles the colloid.

The most interesting thing about pectin in cider is that the traditional method turns it into an asset. Keeving begins with pectin methylesterase — the fruit’s own, in the classical Norman and Herefordshire practice, or an added preparation in modern industrial keeving — stripping the methyl esters off the pectin backbone. That exposes carboxyl groups that carry a negative charge. Add calcium, which is normally present as a salt in the juice or added deliberately, and each calcium ion bridges two chains. The polymer network that forms is calcium pectate: a coherent gel rather than a precipitate.

What makes the gel useful is that it floats. A slow, cold, incipient fermentation generates just enough carbon dioxide for the bubbles to lift the gel to the surface as the chapeau brun, the brown cap, and the maker racks clear juice out from beneath it. The cap takes with it the suspended solids, much of the yeast population and, decisively, most of the assimilable nitrogen. The juice left behind is clean, nutrient-starved and ferments slowly to a natural stop with sugar still in it. This is the traditional route to a sweet cider without added sugar, without sterile filtration and without pasteurisation, and it exists because a structural polysaccharide can be persuaded to form a raft.

Related compounds

Compounds it is formed from, converted into, confused with, or routinely met alongside.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.