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Compound

Lactones

Cyclic esters that give peach and apricot character, formed from fatty acids and often carried in bound form, which is why stone-fruit notes can appear in a cider months after fermentation.

Also called gamma-decalactone, Fruit lactones.

Class
Esters
Formula
Not a single molecule — see below
How often it matters
Specialist — met in particular circumstances

What it does in cider

How it is perceived

What the compound registers as, and at roughly what concentration. Perception is not a property of the molecule alone: sugar, tannin and carbonation all change where a threshold falls.

On threshold

Potent at low concentrations, and more perceptible in a low-pH cider because acidity shifts the equilibrium towards the volatile ring-closed form.

Descriptors it is responsible for

Sensory records that name Lactones as a cause. Each states the perception and the mechanism behind it.

The structure it moves

Structural dimensions this compound contributes to. Direction and amount depend on concentration and on what else is in the drink; the dimensions themselves are set out in full under Sensory.
DimensionWhat it is
Fruit characterHow strongly the drink smells of apple or pear, and of fruit generally.
BodyHow much weight and viscosity the drink has in the mouth.
Fermentation characterAromas made by the ferment rather than carried in from the fruit.

What forms it

Processes that put this compound into the drink, or increase how much of it is there.

Organisms that produce it

Which organism is responsible usually decides whether the compound is a feature or a symptom.

About Lactones

A lactone is an ester where the acid and the alcohol are parts of the same molecule, so the ester bond closes a ring. The ones that matter for aroma are formed from hydroxy fatty acids, and they smell of stone fruit — gamma-decalactone is the classic peach compound, and its relatives give apricot and a creamy coconut note.

Their behaviour in a cider is unusual in one respect. The closed ring is in equilibrium with the open hydroxy acid, which has no aroma, and the equilibrium is pH-dependent: acidic conditions favour the ring. A cider therefore carries a reservoir of potential aroma that is realised to a degree set by its own acidity, and a sharp cider will smell more of stone fruit than a low-acid one carrying the same total quantity.

They are also slow. Conversion from precursors continues through maturation, so a stone-fruit character that was not evident at bottling can be clear a year later — one of the few aroma changes in a maturing cider that runs upwards while everything else is fading. They should be kept distinct from the oak lactones, which are a different set of compounds arriving from wood rather than from fruit or ferment.

Related compounds

Compounds it is formed from, converted into, confused with, or routinely met alongside.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.