Skip to content
CiderHQ
Search

Compound

Sorbic acid

A preservative that stops yeast but not bacteria, and whose effectiveness — like that of sulphur dioxide — depends on pH, because only the undissociated molecule works.

Also called Hexa-2,4-dienoic acid.

Class
Additives and processing aids
Formula
C6H8O2
How often it matters
Regularly encountered

What it does in cider

How it is perceived

What the compound registers as, and at roughly what concentration. Perception is not a property of the molecule alone: sugar, tannin and carbonation all change where a threshold falls.

On threshold

Sorbic acid itself is largely tasteless in cider at permitted levels. What is tasted is the geranium compound formed when lactic bacteria metabolise it, which is perceptible at extremely low concentration.

Descriptors it is responsible for

Sensory records that name Sorbic acid as a cause. Each states the perception and the mechanism behind it.

The structure it moves

Structural dimensions this compound contributes to. Direction and amount depend on concentration and on what else is in the drink; the dimensions themselves are set out in full under Sensory.
DimensionWhat it is
Fermentation characterAromas made by the ferment rather than carried in from the fruit.

What forms it

Processes that put this compound into the drink, or increase how much of it is there.

Faults it is implicated in

Being implicated is not the same as being a fault. Several of the compounds on this site are ordinary constituents of a sound cider and define a named fault only above a concentration.

Organisms that produce it

Which organism is responsible usually decides whether the compound is a feature or a symptom.

About Sorbic acid

Sorbic acid belongs to the same family of weak-acid preservatives as sulphur dioxide and benzoic acid, and it works the same way. The undissociated molecule is uncharged and lipid-soluble, so it crosses the cell membrane freely; inside, at the higher internal pH, it dissociates and acidifies the cytoplasm, and the cell spends its energy pumping protons back out instead of growing. Charged sorbate ions cannot cross the membrane and do nothing. This is why every weak-acid preservative is a pH-dependent preservative.

Sorbic acid’s dissociation constant is high enough — a pKa around 4.8 — that a useful fraction remains undissociated at any pH a cider reaches, which makes it more forgiving than sulphur dioxide in a high-pH cider. Its limitation is a different one: it acts on yeasts and moulds and barely troubles lactic acid bacteria at all.

That gap is not merely a shortfall in protection; it is an active hazard. Lactic acid bacteria can reduce sorbic acid and the product rearranges to 2-ethoxyhexa-3,5-diene, which smells intensely of crushed geranium leaf and is detectable at concentrations so low that the affected cider is unsaleable. Sorbate is therefore only ever used alongside enough free sulphur dioxide to suppress the bacteria, and permitted concentrations are set by food additive law in each jurisdiction rather than by the maker.

Related compounds

Compounds it is formed from, converted into, confused with, or routinely met alongside.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.