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Compound

Potassium sorbate

The soluble salt in which sorbic acid is actually added, used to hold sweetness in a bottled cider, and dangerous to use without sulphite because of what lactic bacteria do to it.

Class
Additives and processing aids
Formula
C6H7KO2
How often it matters
Regularly encountered

What it does in cider

How it is perceived

What the compound registers as, and at roughly what concentration. Perception is not a property of the molecule alone: sugar, tannin and carbonation all change where a threshold falls.

On threshold

The geranium compound is perceptible at extremely low concentration and is not removable, so the failure mode of a sorbate addition is far more damaging than the addition is beneficial.

Descriptors it is responsible for

Sensory records that name Potassium sorbate as a cause. Each states the perception and the mechanism behind it.

The structure it moves

Structural dimensions this compound contributes to. Direction and amount depend on concentration and on what else is in the drink; the dimensions themselves are set out in full under Sensory.
DimensionWhat it is
Fermentation characterAromas made by the ferment rather than carried in from the fruit.

What forms it

Processes that put this compound into the drink, or increase how much of it is there.

Faults it is implicated in

Being implicated is not the same as being a fault. Several of the compounds on this site are ordinary constituents of a sound cider and define a named fault only above a concentration.

Organisms that produce it

Which organism is responsible usually decides whether the compound is a feature or a symptom.

About Potassium sorbate

Sorbic acid is barely soluble in water, so it is added as its potassium salt, which is very soluble. Once in the cider the salt dissociates and an equilibrium establishes between sorbate ion and sorbic acid, with only the undissociated acid able to enter a yeast cell and interfere with it. Everything about dosing therefore depends on pH, in the same way it does for sulphur dioxide, though sorbic acid’s higher dissociation constant makes it more forgiving across the range cider occupies.

What it is for is narrow and worth stating precisely: it prevents yeast from growing again in a cider that has been sweetened and packaged. It will not stop an active fermentation, it will not kill an established population, and it does nothing about bacteria. A producer using it must first have a cider that is genuinely finished, and must remove or reduce the yeast population by racking, fining or filtration before adding it.

The reason it is never used alone is the geranium fault. Lactic acid bacteria reduce sorbic acid to sorbyl alcohol, which rearranges under acid conditions to 2-ethoxyhexa-3,5-diene — a compound that smells of crushed geranium leaf, is detectable at vanishingly small concentrations, and cannot be removed. Adequate free sulphur dioxide suppresses the bacteria and prevents the sequence, which is why sorbate and sulphite are always discussed as a pair. Permitted maximum concentrations are set by food additive law in each jurisdiction.

Related compounds

Compounds it is formed from, converted into, confused with, or routinely met alongside.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.