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Compound

Amino acids

The largest usable nitrogen fraction in apple juice, and the raw material from which yeast builds both its own protein and most of the aroma compounds a cider carries.

Also called Free amino nitrogen, Asparagine and aspartic acid.

Class
Nitrogen compounds
Formula
Not a single molecule — see below
How often it matters
Regularly encountered

What it does in cider

Measured figures

Shown as they were measured, with the context each was taken in. They are not averaged: a concentration recorded in one country's fruit in one decade is not a constant.

Free amino nitrogen51.0 mg/L

Virginia, United States, 2014–2015 · 108 samples · Enzymatic primary amino nitrogen assay (K-PANOPA) · Boudreau, Peck, O’Keefe and Stewart, Food Science & Nutrition 6(1):119–123

The mean, with a standard error of 3 mg N/L. Free amino nitrogen made up about 85% of all the assimilable nitrogen in these juices and tracked the total closely, which is the opposite of the grape case and means an apple juice can in practice be assessed on this fraction alone.

The amino-acid fraction of the nitrogen yeast can use. Measured in milligrams per litre.

What forms it

Processes that put this compound into the drink, or increase how much of it is there.

What removes or limits it

Processes that reduce it, hold it below a threshold, or stop it forming in the first place.

Faults it is implicated in

Being implicated is not the same as being a fault. Several of the compounds on this site are ordinary constituents of a sound cider and define a named fault only above a concentration.

Organisms that produce it

Which organism is responsible usually decides whether the compound is a feature or a symptom.

Nitrogen and sulphide are not a straight lineTwo yeast strains fermenting one apple juice at three nitrogen levels. The middle level produced the most hydrogen sulphide; one strain produced none at any level.0100200300123.750Low22.3 mg/L288.250Intermediate144.3 mg/L44.1250High369.3 mg/Lµg H₂S per 100 mLDiammonium phosphate addedStrain UCD522Strain UCD932 — none detectedBase juice 63.7 mg N/L, fermented at 20 °C
Two yeast strains fermenting one apple juice at three nitrogen levels. The middle level produced the most hydrogen sulphide; one strain produced none at any level.
Described in full
Shape
A grouped bar chart. Three groups along the bottom are the three diammonium phosphate treatments — low at 22.3, intermediate at 144.3 and high at 369.3 milligrams per litre, all added to one juice that already carried 63.7 milligrams of assimilable nitrogen per litre. Each group holds two bars, one per yeast strain, and each bar is labelled with its value.
Strain UCD522
Low 123.75, intermediate 288.25, high 44.125 micrograms of hydrogen sulphide per 100 millilitres. The intermediate treatment produced twice what the low one did and more than six times what the high one did.
Strain UCD932
Zero at all three treatments. No hydrogen sulphide was detected from this strain regardless of how much nitrogen it was given, so its three bars are drawn as a flat line at the axis and labelled “none detected”.
The threshold line
A dashed horizontal reference is not drawn, because the sensory threshold — about 0.41 micrograms per litre — is roughly a thousandth of the smallest bar here and would sit indistinguishably on the axis. That is the point worth taking away: every one of these fermentations was far above the concentration a nose can find.
What it corrects
The common rule is that low nitrogen causes sulphide and adding nutrient cures it. On these data, adding some nutrient was worse than adding none, and adding a lot was better than either — but only for the strain that made sulphide at all. Strain choice came before nitrogen.
Scope
One juice, one temperature — 20 degrees Celsius — one pitching rate, two strains, three treatments, in triplicate. The shape of the relationship is the finding; the numbers belong to this experiment.

About Amino acids

Most of the nitrogen a cider ferment can use arrives as free amino acids, and in apple juice asparagine and aspartic acid usually lead the list. Yeast takes them up in a preferred order, uses the nitrogen, and disposes of the leftover carbon skeletons as higher alcohols — which means the amino acid composition of a juice is, quite directly, a specification for the fermentation aroma that juice can produce. Leucine becomes isoamyl alcohol and then the banana ester; phenylalanine becomes 2-phenylethanol and the rose note.

Proline is the awkward exception. Apple juice carries a good deal of it, it appears in a total nitrogen analysis, and yeast cannot use it without oxygen. A juice can therefore look better nourished than it is, and this is one reason assimilable nitrogen is measured specifically rather than inferred from total nitrogen.

Amino acids have a second life after fermentation. As yeast cells autolyse on the lees they release their contents back into the cider, which is part of the textural gain from lees ageing and also a nutrient supply for anything that arrives afterwards — Dekkera, lactic bacteria, and the organisms that decarboxylate amino acids into biogenic amines. Extended lees contact is therefore a technique that requires the rest of the cellar to be in order.

Related compounds

Compounds it is formed from, converted into, confused with, or routinely met alongside.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.