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Fault

Hydrogen sulphide

A rotten-egg or drain smell from hydrogen sulphide produced by stressed yeast, usually the first visible consequence of a nitrogen-short juice.

Also called rotten egg, H2S, sulphide.

Severity
Quality — the drink is worse for it
Where it starts
Fermentation, Juice treatment, Orchard, Maturation
Can it be fixed?
Yes, if caught in time
When you notice it
Fermentation
Signs
5 recorded

What it is

Hydrogen sulphide is a gas produced by yeast during fermentation, mainly when the yeast is short of assimilable nitrogen. It has an extremely low odour threshold and smells of rotten eggs, drains or struck flint depending on concentration. Caught during active fermentation it is often the easiest cider fault to deal with, because carbon dioxide is still being generated and will carry it off. Left in the cider it reacts onwards into compounds that are far more stable and far harder to remove.

What you notice

Grouped by sense, because that is how the fault presents itself rather than how it works.

On the nose

  • A rotten-egg smell from the airlock or the top of the vessel during fermentation
  • A drain or blocked-sink note in a young cider
  • A struck-flint or matchstick edge at low concentration, easily mistaken for minerality

How the batch behaves

  • A ferment that is also slow, stalling or unusually quietThe nitrogen shortage that produces sulphide is the same shortage that slows the ferment.

On the palate

  • A metallic, slightly sour taste in the finish

The words for it: Rotten egg, Struck match. Each links to what produces it.

When it appears. During active fermentation, usually in the first week, and typically when the ferment is most vigorous. A rotten-egg smell that first appears months later is almost certainly something else.

What is known about detecting it

Detectable at very low concentration — this is among the most readily smelled compounds in a cider house — which is why it is usually caught while it can still be dealt with by splash-racking. That short window is the whole practical significance of the fault.

Song, Gibney, Cheng, Liu and Peck, Frontiers in Microbiology 11:1264, Andrew Lea

What it is mistaken for, and how to tell

One observation per rival, chosen because it separates them rather than because it describes either. Several of these are not faults at all — a style feature, a normal outcome, or the fruit behaving as it does.

What is actually happening

The chemistry or microbiology behind it. Understanding the mechanism is what makes the prevention make sense rather than being a list of rules.

Yeast needs sulphur to build the amino acids methionine and cysteine. It obtains it by taking up sulphate from the juice and reducing it, through the sulphate reduction pathway, to sulphide. Sulphide is then normally fixed immediately onto a nitrogen-containing carbon skeleton to make those amino acids.

If the yeast runs short of assimilable nitrogen, the acceptor molecules are not available, and the sulphide generated by the pathway has nowhere to go. It leaves the cell as hydrogen sulphide gas. This is why a fault that smells of sulphur is nearly always a nitrogen problem, and why adding sulphur-containing anything makes it worse rather than better.

Cider juice is characteristically low in yeast assimilable nitrogen compared with grape must, particularly juice from traditional bittersweet fruit grown in unfertilised orchards, and this is the central reason the fault is common in cider and less so in wine. Thiamine deficiency and elemental sulphur residues from orchard sprays are secondary contributors.

The compound is highly volatile and, while fermentation is vigorous, is stripped continuously by the escaping carbon dioxide. Once the ferment slows, hydrogen sulphide remaining in the cider begins to react with ethanol and with other components to form thiols and disulphides, which are much less volatile, smell of onion, rubber and cooked cabbage, and do not blow off.

How it happens

Causes, with the stage each originates at and how often it is the explanation.
CauseStageHow often
Juice low in yeast assimilable nitrogen, especially from unfertilised traditional orchardsFermentationcommon
A juice clarified very thoroughly before fermentation, removing solids that carried nutrientJuice treatmentoccasional
Yeast strain selected without regard to its nitrogen demandFermentationoccasional
Elemental sulphur residue on fruit from late orchard spraysOrchardoccasional
Fermentation temperature high enough to stress the yeast populationFermentationoccasional
Cider left on heavy lees after fermentation, where autolysing yeast releases sulphur compoundsMaturationoccasional

Can it be put right?

Most cider faults cannot be reversed. Where that is the answer it is given plainly — an honest 'this batch is what it is' is more useful than a procedure that will not work.

Corrective options and how well each actually works.
OptionEffectivenessWhat it involves
Rack the cider with deliberate splashing while fermentation is still activeReliableThe standard response and genuinely effective, because hydrogen sulphide is volatile and the carbon dioxide still being produced protects the cider from the oxygen introduced. This only holds during active fermentation — the same action on a finished cider oxidises it.
Add yeast nutrient at the first sign, early in the fermentPartialAddresses the cause rather than the symptom, but only while there is enough fermentation left for it to matter. Use the supplier’s rate for the product; nutrient blends differ substantially in composition.
Wait for it to blow off on its ownPartialOften works during a vigorous ferment. Risky as a strategy, because the window closes when fermentation slows and what remains converts to compounds that will not leave.
Remove sulphide from a finished, aged ciderUnlikely to workCopper treatment is used commercially and is not something to improvise: copper is itself a taint and an oxidation catalyst, dosing is tightly regulated, and residual copper limits apply. If the cider has aged, the compounds present are probably no longer hydrogen sulphide at all.
On dosages

CiderHQ gives no additive dosage figures. An addition is a food-safety decision that depends on legal limits, on the juice in front of you and on what you are protecting against, and the right figure comes from your supplier’s or regulator’s own guidance rather than from a general reference.

Preventing it

More on this

Hydrogen sulphide is the fault that rewards paying attention, because the difference between a nuisance and a permanent problem is measured in days. During a vigorous ferment it is a signal, not yet damage; a fortnight later it is a different set of molecules that no amount of racking will shift.

It is also the most direct sensory evidence of the structural nitrogen problem in cider. Apple juice from traditional orchards, particularly from bittersweet fruit on unfertilised standard trees, is often substantially poorer in assimilable nitrogen than grape must, and much of what goes wrong in cider fermentation traces back to that single fact.

A common misreading is to treat the smell as an infection. It is not: it is ordinary brewing yeast doing ordinary metabolism under stress, and the vessel is not contaminated. The response is nutritional and physical, not sanitary.

At the very low end the same compound is not necessarily unwelcome. A faint struck-flint character in a young cider is often read as minerality, and whether that is a fault is a question about the drink intended rather than about the chemistry.

The compounds involved

The organisms involved

Where in the process it arises

Faults it is confused with

These present similarly. What separates them is set out on each page.

Where this comes up in a guide

The link lands on the step where the fault arises rather than at the top of the pathway, because that is where the decision that causes it is taken.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.