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Compound

Biogenic amines

Amines produced when bacteria decarboxylate amino acids, associated with long lees contact at high pH and low sulphite, and a reason bacterial activity is managed rather than simply tolerated.

Also called Histamine, Tyramine, Putrescine.

Class
Nitrogen compounds
Formula
Not a single molecule — see below
How often it matters
Occasional

What it does in cider

How it is perceived

What the compound registers as, and at roughly what concentration. Perception is not a property of the molecule alone: sugar, tannin and carbonation all change where a threshold falls.

On threshold

Generally present well below any sensory threshold. Their significance is compositional rather than organoleptic, and a cider carrying them usually tastes of the other products of the same bacterial activity instead.

Descriptors it is responsible for

Sensory records that name Biogenic amines as a cause. Each states the perception and the mechanism behind it.

The structure it moves

Structural dimensions this compound contributes to. Direction and amount depend on concentration and on what else is in the drink; the dimensions themselves are set out in full under Sensory.
DimensionWhat it is
Fermentation characterAromas made by the ferment rather than carried in from the fruit.

What forms it

Processes that put this compound into the drink, or increase how much of it is there.

What removes or limits it

Processes that reduce it, hold it below a threshold, or stop it forming in the first place.

Faults it is implicated in

Being implicated is not the same as being a fault. Several of the compounds on this site are ordinary constituents of a sound cider and define a named fault only above a concentration.

Organisms that produce it

Which organism is responsible usually decides whether the compound is a feature or a symptom.

About Biogenic amines

Bacteria facing an acidic environment can gain a little protection by decarboxylating an amino acid: the reaction consumes a proton and yields an amine. Histidine becomes histamine, tyrosine becomes tyramine, arginine and ornithine become putrescine. In a cider these reactions run where the raw material and the organisms coincide — which means after malolactic fermentation, on lees rich in autolysed yeast, in a cider whose pH is high and whose sulphite is low.

The variability is the practical point. Strains differ by orders of magnitude in their capacity to produce these compounds, and a selected malolactic culture chosen for low amine production behaves quite differently from whatever happens to be living in an old barrel. This is one of the substantive arguments for inoculating a malolactic fermentation rather than allowing one, in a cellar where bacterial activity is wanted at all.

Reported concentrations in cider are generally low, and this record is not a warning about drinking cider. It is a note about cellar practice: the conditions that produce biogenic amines are the same ones that produce ropiness, mousiness and lactic off-flavours, and controlling pH, sulphite and lees contact addresses all of them at once.

Related compounds

Compounds it is formed from, converted into, confused with, or routinely met alongside.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.