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Fermentation

Malolactic fermentation

A bacterial conversion of sharp malic acid into softer lactic acid, which lowers acidity, changes aroma, and in most traditional cider happens whether it was planned or not.

Known as Fermentation malolactique where it originates. Also called MLF, Malolactic conversion.

Stage
Fermentation
Traditional in
Asturias, Basque Country, Normandy, Pays d’Auge and 3 more
What it most changes
Acidity down, freshness down
Safety
None recorded

What it is

Malolactic fermentation is not a fermentation in the yeast sense at all. It is a bacterial decarboxylation in which lactic acid bacteria convert L-malic acid, the dominant and sharpest acid in apple juice, into L-lactic acid and carbon dioxide. Because malic acid carries two carboxyl groups and lactic acid only one, the conversion removes roughly half the acid’s titratable contribution and raises pH. Sensorially the drink loses hardness and gains a rounder, softer, sometimes faintly dairy or nutty character. In cider it usually happens spontaneously in the spring following the harvest, as cellar temperatures rise and the bacteria that survived the primary ferment become active.

Malic acid to lactic acidThe malolactic conversion and its three consequences for the palate.Malic acidtwo acid groupsOenococcus oeniLactic acidone acid groupcarbon dioxide leavesWhat changes on the palateAcidity fallsone group lostpH risesless protectedButter notefrom diacetylWanted in some styles, a fault in others
The malolactic conversion and its three consequences for the palate.
Described in full
The reaction
Malic acid, which carries two acid groups, is decarboxylated to lactic acid, which carries one, releasing carbon dioxide. Nothing is fermented in the ordinary sense: no sugar is consumed and no alcohol is made.
What performs it
Lactic acid bacteria, chiefly Oenococcus oeni and Lactiplantibacillus plantarum. They arrive on the fruit and in the vessel, and in traditional cidermaking they are rarely inoculated.
Acidity falls
Losing one of two acid groups roughly halves the acid contribution of every malic molecule converted. Titratable acidity drops and the cider tastes rounder.
pH rises
The same change raises pH, which matters because a higher pH is a less protected cider. Malolactic makes a drink softer and simultaneously more vulnerable to spoilage.
A buttery note may appear
Diacetyl is a by-product. In small amounts it reads as butter or butterscotch, which is traditional in some styles and a fault in a fresh, fruit-driven one.
Carbon dioxide is released
A slow bead in a maturing vessel is often malolactic rather than residual fermentation. In a sealed bottle, an unfinished malolactic is a source of unplanned pressure.
Not always wanted
A cider made for freshness is usually kept below the pH and temperature where the bacteria establish, or filtered and sulphited to prevent it. The same conversion is a goal in one cellar and a fault in another.

Why it is used

How it works

What it changes

The direction this step pushes the finished drink in, dimension by dimension. A direction, not a measurement: how far it moves depends on the juice, the temperature and how the step is carried out.

Effect on each sensory dimension. Hover or focus a dimension name for what that dimension means on CiderHQ.
DimensionDirectionWhy
AcidityLowersReplacing a dicarboxylic acid with a monocarboxylic one removes about half the titratable acid contribution of every molecule converted, and raises pH with it.
FreshnessLowersMalic acid is the component the palate reads as crisp and apple-like, and lactic acid does not substitute for it.
BodyRaisesThe loss of sharp acid and the arrival of lactic and ester character shift the perceived texture from angular to rounded, an effect of contrast rather than of added substance.
Fermentation characterRaisesDiacetyl, acetoin and ethyl lactate produced during and after the conversion add a lactic, buttery or nutty layer that was not present in the young cider.
Fruit characterLowersFresh apple aroma is closely tied to malic acidity, and the same bacterial activity also metabolises some of the fruit-derived compounds that supported it.

The chemistry and the organisms

What is actually being changed, and by what. Each entry says what that compound or organism does in cider generally; this page is one place it does it.

Compounds involved

Organisms involved

Where it is traditional

The places this step belongs to as a matter of practice. It is not a claim of exclusivity — a method can be traditional in one region and perfectly ordinary in another.

What it is done with

What can go wrong

Faults that begin at this step, or that this step makes more likely. Each one is set out with its causes and whether it can be put right.

Styles it produces

Categories in which this step is characteristic or required. Some name it in their definition; for others it is simply how they have always been made.

Recorded figures

Shown with the place, period and method each was taken under, and never averaged: the same step run in another cellar genuinely gives a different number.

Microbial population6.0 log CFU/mL

context not recorded · Reported as the level Oenococcus oeni proliferates past in wine and cider after alcoholic fermentation · Campbell-Sills, El Khoury, Favier and others, Genome Biology and Evolution 7(6):1506–1518

A threshold for the process rather than a target for a maker. Below it the conversion is slow and uncertain; past it the organism is the only culturable bacterium present and the conversion runs to completion. Nothing about the figure says how long that takes, which depends on temperature, pH and free sulphur dioxide.

Viable cells per millilitre, on the log scale. What separates an organism that is present from one that is running the ferment. Measured in log colony-forming units per millilitre.

Lactic acid4.0–4.7 g/L

Villaviciosa, Asturias, Spain, 2001–2002 · HPLC on finished sidra natural after spontaneous malolactic conversion by the indigenous flora · Suárez Valles, Pando Bedriñana, Fernández Tascón, Querol Simón and Rodríguez Madrera, Food Microbiology 24(1):25–31

What the conversion actually leaves behind, measured in the same ciders whose malic acid had fallen below 0.5 g/L. Reading the two together is the clearest statement of the process there is: the acid did not go away, it changed to a milder one, and lactic acid became the major acid in the cider.

The acid malolactic bacteria make out of malic acid — softer on the palate than the acid it replaces, and in a fully malolactic cider the dominant one. Measured in grams per litre.

More on malolactic fermentation

The reaction itself is disarmingly simple. A single enzyme removes one carboxyl group from L-malate and releases it as carbon dioxide, leaving L-lactate. There is no chain of intermediates and no net gain of carbon for the organism; what the bacterium gets is a proton gradient it can use, which is why the conversion proceeds vigorously in a medium that offers it little else. The consequence for the drink is arithmetical: malic acid is diprotic, lactic acid is monoprotic, so each molecule converted contributes about half as much to titratable acidity as it did, and pH rises accordingly. In a bittersharp cider that has fermented to dryness this is often the difference between a drink that is uncomfortably hard and one that is balanced.

Which organism does it matters more in cider than the textbooks written for wine suggest. Oenococcus oeni is the well-behaved case: acid- and ethanol-tolerant, and the species most commercial malolactic cultures are built from. But cider is fermented cooler than wine, often at higher pH, and frequently without sulphite, and that combination opens the door to lactobacilli that would not establish in a wine cellar. Lactobacillus collinoides is the cider-specific problem child. Given glycerol it can produce 3-hydroxypropionaldehyde, which dehydrates to acrolein and reacts with phenolics to give a searing, persistent bitterness that cannot be blended away. Related organisms produce exopolysaccharide and turn a cider ropy, or generate tetrahydropyridines and the mousy off-note that only appears retronasally after swallowing, or produce the raspberry-like framboise character from fructose. A malolactic conversion is a bacterial ferment, and bacterial ferments in a nutrient-poor, low-alcohol medium are not automatically benign.

Traditions treat it very differently, and none of them treats it the way modern winemaking does. In Asturias and the Basque Country the conversion is expected: sidra natural and sagardoa are fermented spontaneously in wood and go through malolactic as a matter of course, and the resulting lactic and slightly volatile profile is what the appellations and the drinking public recognise as correct. English farmhouse and Norman practice likewise let it happen in the spring, and much of what the West Country palate reads as farmhouse character is post-malolactic. Modern producers making a fresh, aromatic, acid-driven cider often want the opposite, and prevent it deliberately by keeping the cider cold, maintaining free sulphur dioxide, filtering out the bacteria, or all three. Producers making a sparkling cider by any bottle-fermented method have a more urgent reason to settle the question before packaging.

That is the practical decision: not whether malolactic conversion is good, but whether it will happen in the tank where it can be watched or in the bottle where it cannot. A cider bottled with malic acid still present and viable lactic acid bacteria in it will convert eventually, releasing carbon dioxide into a package that may not be built for it, dropping a haze, and shifting the drink’s balance months after it left the producer. The conversion is also close to irreversible: acid can be added back, but the aromatic and textural change cannot be undone, and a low-acid bittersweet cider pushed through a complete malolactic can end up flabby with nothing to give it definition. Makers who want it monitor for the disappearance of malic acid by paper chromatography or enzymatic assay rather than by taste, and those who do not want it act before the cellar warms rather than after.

Related processes

Steps that sit alongside this one, replace it, or depend on it having been done.

What people ask next

Questions readers ask about the things this page mentions. Each one goes to the section that answers it rather than to a page written to receive the question.

Where to go next

Sources

What this page rests on. Where a source is marked as registered rather than read, CiderHQ is recording that the body is authoritative on the subject without claiming to have worked through the document itself. See our evidence policy for what each state means.